
F22 (EN 1.7380) is a low-alloy, heat-resistant chromium-molybdenum steel. This valve maintains its structural strength and creep resistance at temperatures up to 600°C, and exhibits extremely high resistance to hydrogen degradation and high-temperature hydrogen erosion within a temperature range of 500°C.
F22 valves exhibit excellent allowable stress performance in the 450-540℃ range, making them a classic material for subcritical thermal power systems.
F22 valves demonstrate good resistance to high-temperature hydrogen-induced cracking (HIC) and hydrogen embrittlement, and are widely used in hydrogenation plants.
With a Cr content of 2.25%, F22 valves exhibit better resistance to H₂S sulfide corrosion than F11, but weaker than F5 (5Cr-0.5Mo).
When the operating temperature of F22 valves exceeds 540℃, their creep strength rapidly decreases, therefore they cannot be used in supercritical units.
In high-temperature, high-concentration H₂S media, the sulfide corrosion rate of F22 valves is higher than that of F5 valves, and strong corrosive media can cause oxidation-sulfide cross-corrosion.
When the operating temperature of F22 valves exceeds 550℃, the high-temperature oxidation rate increases significantly.
① Main steam pipelines of subcritical units;
② Subcritical boiler systems with steam temperatures ≤ 540℃;
① Inlet and outlet of hydrogenation reactors, high-temperature hydrogen-containment pipelines;
② Hydrocracking, residue hydrogenation, high-temperature and high-pressure hydrogen environment;
High-temperature and high-pressure hydrogen-containing process pipelines;
High-temperature process steam systems with temperatures between 480-540℃;
① When the medium contains a high concentration of H₂S: F5 valves should be prioritized, and F22 valves are not recommended;
② When the medium has strong sulfide corrosion: F5 valves should be prioritized, and F22 valves are not recommended;
③ When the temperature is >540℃: F91 valves should be prioritized.